Cationic Tris N-Heterocyclic Carbene Rhodium Carbonyl Complexes:  Molecular Structures and Solution NMR Studies

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Burling, Suzanne; Douglas, Susie; Mahon, Mary F.; Nama, Devendrababu; Pregosin, Paul S.; Whittlesey, Michael K.;
(2006)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/om060202p.s002, doi: 10.1021/om060202p.s004, doi: 10.1021/om060202p.s003
  • Subject: Biotechnology | CF | NHC | HOESY | Medicine | CO | 1 H NMR spectra | 40 kJ mol | i Pr 2 | NMR measurements show | Genetics | BAr 4 F | line shape analyses | Rh | Biochemistry | PF 6 | Biophysics | Immunology | PGSE | ICy | Solution NMR Studies
    • FOR: 29999 Physical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The cationic N-heterocyclic carbene (NHC) rhodium complexes [Rh(NHC)<sub>3</sub>(CO)]<sup>+</sup> (NHC = ICy (<b>1</b>), I<sup>i</sup>Pr<sub>2</sub>Me<sub>2</sub> (<b>2</b>)) have been isolated from the reactions of RhH(PPh<sub>3</sub>)<sub>3</sub>(CO) with the free ... View more
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