AlCl3‑Catalyzed Annulations of Ynamides Involving a Torquoselective Process for the Simultaneous Control of Central and Axial Chirality

Yang, Yanyan; Liu, Hongxu; Peng, Cheng; Wu, Jie; Zhang, Jingyi; Qiao, Yan; Wang, Xiao-Na; Chang, Junbiao;

A highly torquoselective process for simultaneous control of central and axial chirality by the annulation of terminally substituted ynamides with <i>o</i>-quinone methides is reported. In the presence of AlCl<sub>3</sub>, a sequence comprising a [2 + 2] cyc... View more
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