Phosphoramidite Gold(I)-Catalyzed Diastereo- and Enantioselective Synthesis of 3,4-Substituted Pyrrolidines

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González, Ana Z.; Benitez, Diego; Tkatchouk, Ekaterina; Goddard, William A.; Toste, F. Dean;
(2011)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja200084a.s004, doi: 10.1021/ja200084a.s003, doi: 10.1021/ja200084a.s005, doi: 10.1021/ja200084a.s002
  • Subject: Molecular Biology | Enantioselective Synthesis | synthesis | Microbiology | utility | reaction proceeds | phosphoramidite ligands | allenene | cycloaddition | DFT | Biochemistry | exogenous nucleophile | diastereoselective construction | Biophysics | Immunology | stereogenic centers | enantioselective AuI catalysis
    • FOR: 59999 Environmental Sciences not elsewhere classified | 110309 Infectious Diseases | 60506 Virology | 39999 Chemical Sciences not elsewhere classified

In this article the utility of phosphoramidite ligands in enantioselective Au<sup>I</sup> catalysis was explored in the development of highly diastereo- and enantioselective Au<sup>I</sup>-catalyzed cycloadditions of allenenes. A Au<sup>I</sup>-catalyzed synthesis of 3,... View more
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