The First Framework Solid Composed of Vanadosilicate Clusters

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Tripathi, Akhilesh; Hughbanks, Timothy; Clearfield, Abraham;
(2003)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja0365173.s001, doi: 10.1021/ja0365173.s002
  • Subject: polyoxovanadogermanate | POVG | Sociology | H 4 V 18 O 46 | GeOH | C 4 H 14 N 2 | covalently | isostructural vanadosilicate clusters | diaminobutane | Space Science | Ecology | Composed | Pharmacology | Science Policy | Communication | hydrothermal conditions | network structure | synthesis | vanadium polyhedra | First Framework | Medicine | SiO 2 | Computational Biology | V 14 O 44 | framework | Vanadosilicate Clusters | GeO 2 | VO | 8 C 4 H 12 N 2 | amine
    • FOR: 69999 Biological Sciences not elsewhere classified

In this Communication, we report the first example of a network structure composed of vanadosilicate clusters. We utilized hydrothermal conditions to synthesize a polyoxovanadogermanate (POVG):  (C<sub>4</sub>H<sub>14</sub>N<sub>2</sub>)<sub>4</sub>[V<sub>14</sub>O<sub>... View more
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