A Systematic Study of Functionalized Oxiranes as Initiating Groups for Cationic Polycyclization Reactions

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Rajendar, Goreti; Corey, E. J.;
(2015)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jacs.5b03229.s004, doi: 10.1021/jacs.5b03229.s003
  • Subject: cationic polycyclization reactions | Lewis acid activation | Biotechnology | cationic cyclization | Neuroscience | Developmental Biology | Cationic Polycyclization ReactionsThree | Katsuki | Functionalized Oxiranes | Computational Biology | hydroxymethyl oxiranes | allylic alcohols | Cell Biology | Genetics | Evolutionary Biology | epoxidation | Systematic Study | Biochemistry | Pharmacology | chiral oxiranes | form chiral polycycles
    • FOR: 111714 Mental Health | 19999 Mathematical Sciences not elsewhere classified

Three different methods have been developed that effectively utilize chiral oxiranes derived from Katsuki–Sharpless epoxidation of allylic alcohols as initiating groups for cationic cyclization of unsaturated substrates to form chiral polycycles. This type o... View more
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