Heterometallic Chains and Clusters with Gold-Transition Metal Bonds: Synthesis and Interconversion

Sculfort, Sabrina; Welter, Richard; Braunstein, Pierre;

Anionic, metal−metal bonded heterotrinuclear chain complexes of the type [M{MoCp(CO)<sub>3</sub>}<sub>2</sub>]<sup>−</sup> with M = Cu(I), Ag(I), and Au(I) have been prepared by reaction between a d<sup>10</sup> metal precursor complex and the carbonylmetalate [MoCp(CO)... View more
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