Thermal 1,3-Trityl Migrations in Diels−Alder Domino Reactions of 1-Trityl-4-vinyl-1H-imidazoles

Cotterill, Lynsey J.; Harrington, Ross W.; Clegg, William; Hall, Michael J.;

Under thermal conditions, tritylimidazoles have been shown to undergo sterically driven N→N trityl migrations, in disagreement with previously published reports. These migrations are a key step in several highly diastereoselective domino reaction sequences (Diels−Alder,... View more
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