Single-Molecule Magnetism in a Family of {CoIII2DyIII2} Butterfly Complexes: Effects of Ligand Replacement on the Dynamics of Magnetic Relaxation

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Langley, Stuart K.; Ungur, Liviu; Chilton, Nicholas F.; Moubaraki, Boujemaa; Chibotaru, Liviu F.; Murray, Keith S.;
(2014)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic4029645.s001, doi: 10.1021/ic4029645.s002, doi: 10.1021/ic4029645.s003
  • Subject: anisotropy barrier | DyIII ions | Neuroscience | nonmagnetic ground states | diamagnetic ground states | compounds display | CoIII 2DyIII Butterfly Complexes | ground Kramers doublets | 2CoIII | SMM | Ab initio calculations | quantum tunneling time scales | diamagnetic CoIII ions | butterfly type core | Biochemistry | Magnetic RelaxationThe synthesis | Biophysics
    • FOR: 29999 Physical Sciences not elsewhere classified | 111714 Mental Health | 39999 Chemical Sciences not elsewhere classified

The synthesis and structural characterization of four related heterometallic complexes of formulas [Dy<sup>III</sup><sub>2</sub>Co<sup>III</sup><sub>2</sub>(OMe)<sub>2</sub>­(teaH)<sub>2</sub>(O<sub>2</sub>CPh)<sub>4</sub>(MeOH)<sub>4</sub>]­(NO<sub>3</sub>)<sub>2... View more
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