Cyclopalladation of the Prochiral (Di-tert-butyl)(diphenylmethyl)phosphine:  Kinetic Lability of the Corresponding (+)-Phosphapalladacyclic Pd−C Bond and the Reluctance of the Phosphine to Bind in a Monodentate Fashion

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Ng, Joseph Kok-Peng; Chen, Shuli; Li, Yongxin; Tan, Geok-Kheng; Koh, Lip-Lin; Leung, Pak-Hing;
(2007)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic0702320.s002, doi: 10.1021/ic0702320.s003
  • Subject: room temperature | tert | bond cleavage | dimer | coordination | butyl | Space Science | palladacycle | phosphine | Biophysics | Monodentate Fashion | monodentate | Lewis acidity | Medicine | ortho palladate | refluxing acetone solution | ortho palladation | derivatized O | Cell Biology | Pd | Biochemistry | NMR spectroscopy | hydrochloric acid
    • FOR: 59999 Environmental Sciences not elsewhere classified | 29999 Physical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The ortho palladation of prochiral (di-<i>tert</i>-butyl)(diphenylmethyl)phosphine proceeded readily to give rise to the dimeric complex, di-μ-chlorobis{[(phenyl)(di-<i>tert</i>-butylphosphino)methyl]phenyl-<i>C</i><i><sup>2</sup></i><sup></sup>, <i>P</i>}dipalladium... View more
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