Dicoordinate Copper(I) Silanechalcogenolates

Dataset UNKNOWN
Medina, Iliana; Jacobsen, Heiko; Mague, Joel T.; Fink, Mark J.;
(2006)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic061579q.s003, doi: 10.1021/ic061579q.s002, doi: 10.1021/ic061579q.s004
  • Subject: Inorganic Chemistry | π delocalization | Cu atoms | tBu 3PCu | Pauli repulsion | Neuroscience | Se | Cell Biology | Biochemistry | complex | interaction | O atom | Cancer | Biophysics | theory calculations | Ph 3SiELi
    • FOR: 29999 Physical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The copper silanechalcogenolates <i><sup>t</sup></i><sup></sup>Bu<sub>3</sub>PCuESiPh<sub>3</sub> (<b>1</b>, E = O; <b>2</b>, E = S; <b>3</b>, E = Se) were prepared from the reaction of [<i><sup>t</sup></i><sup></sup>Bu<sub>3</sub>PCu(CH<sub>3</sub>CN)<sub>3</sub>]BF... View more
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