Charge-Transfer Salts via Cocrystallization of the Cationic Ferrocenyl Donor with Polyoxometalate Acceptors

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Xu, Haisheng; Li, Zhanfeng; Liu, Bin; Xue, Ganglin; Hu, Huaiming; Fu, Feng; Wang, Jiwu;
(2010)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/cg900777g.s001, doi: 10.1021/cg900777g.s002, doi: 10.1021/cg900777g.s003, doi: 10.1021/cg900777g.s004
  • Subject: NBu | fmp | Space Science | emission | donor | fluorescence | Pharmacology | Science Policy | Biophysics | UV | ferrocenylmethylpyridinium | space group Pccn | Cationic Ferrocenyl Donor | salt 4 crystallizes | 12O | 10O | cationic | space group Pbca | salts 1 | Biochemistry | CT transition energies | 6O | POM acceptors | nm
    • FOR: 59999 Environmental Sciences not elsewhere classified | 29999 Physical Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Four new charge-transfer (CT) salts based on the cationic ferrocenylmethylpyridinium (fmp) donor (CpFeCp-CH<sub>2</sub>-Py<sup>+</sup>) and polyoxometalate (POM) acceptors, Lindqvist-type [M<sub>6</sub>O<sub>19</sub>]<sup>2−</sup> (M = Mo or W), the decatungstate isopol... View more
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