A Terminal and Four-Coordinate Titanium Alkylidene Prepared by Oxidatively Induced α-Hydrogen Abstraction

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Basuli, Falguni; Bailey, Brad C.; Tomaszewski, John; Huffman, John C.; Mindiola, Daniel J.;
(2003)

One-electron oxidation of the β-diketiminate titanium(III) bis-neopentyl complex (Nacnac)Ti(CH<sub>2</sub><i><sup>t</sup></i><sup></sup>Bu)<sub>2</sub> (Nacnac = [Ar]NC(Me)CHC(Me)N[Ar], Ar = 2,6-(CHMe<sub>2</sub>)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>) promotes α-abstra... View more
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