Synthesis, Structure, and Reactivity of the Sterically Crowded Th3+ Complex (C5Me5)3Th Including Formation of the Thorium Carbonyl, [(C5Me5)3Th(CO)][BPh4]

Langeslay, Ryan R.; Chen, Guo P.; Windorff, Cory J.; Chan, Alan K.; Ziller, Joseph W.; Furche, Filipp; Evans, William J.;

The Th<sup>3+</sup> complex, (C<sub>5</sub>Me<sub>5</sub>)<sub>3</sub>Th, has been isolated despite the fact that tris­(pentamethylcyclopentadienyl) complexes are highly reactive due to steric crowding and few crystallographically characterizable Th<sup>3+</sup... View more
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