Cp*-Substituted Boron Cations: The Effect of NHC, NHO, and CAAC Ligands

Huang, Jih-Sheng; Lee, Wan-Hua; Shen, Chao-Tang; Lin, Ya-Fan; Liu, Yi-Hung; Peng, Shie-Ming; Chiu, Ching-Wen;
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/acs.inorgchem.6b02336.s003, doi: 10.1021/acs.inorgchem.6b02336.s002
  • Subject: Molecular Biology | Developmental Biology | BH | Microbiology | NHC | Medicine | cyclic alkylamino carbene | Computational Biology | NHO | π- acidic CAAC ligand | boron dications | Biochemistry | sp 2 carbon | hydride addition reaction | electron deficiency
    • FOR: 39999 Chemical Sciences not elsewhere classified

The effect of a ligand on the electron deficiency and Lewis acidity of the Cp*-substituted boron dication has been investigated experimentally and theoretically. In addition to the reported IMes- and N-heterocyclic olefin (NHO)-stabilized boron dications, th... View more
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