Unusual Polybrominated Polypyrazolylborates and Their Copper(I) Complexes:  Synthesis, Characterization, and Catalytic Activity

P. A. Yap, Glen; Jove, Fernando; Urbano, Juan; Alvarez, Eleuterio; Trofimenko, Swiatoslaw; Díaz-Requejo, M. Mar; Pérez, Pedro J.;

Five new homoscorpionate ligands were prepared and structurally characterized as their Tl complexes, three of which, Tl[Tp<sup>Br,Ph,Br</sup>] (<b>1</b>) (Tp = hydrotris(pyrazolyl)borate, Tl[Tp<sup>Br,</sup><i><sup>p</sup></i><sup>-Tοl,Br</sup>] (<b>2</b>), and Tl[Tp... View more
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