Coordination Versatility of Pyridine-Functionalized N-Heterocyclic Carbenes:  A Detailed Study of the Different Activation Procedures. Characterization of New Rh and Ir Compounds and Study of Their Catalytic Activity

Mas-Marzá, Elena; Sanaú, Mercedes; Peris, Eduardo;
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic051272b.s002, doi: 10.1021/ic051272b.s001
  • Subject: Ir Compounds | Coordination Versatility | III | acetylenic carboxylic acids | Medicine | Different Activation Procedures | New Rh | NEt 3 | hydrogen transfer | crystal structures | Catalytic Activity | Biochemistry | MCl | Cancer | Biophysics | reaction procedures | imidazolium salt | NHC complexes
    • FOR: 29999 Physical Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Three different reaction procedures for the coordination of <i>N</i>-<i>n-</i>butyl-<i>N</i>‘-(2-pyridylmethyl)imidazolium salt have produced new N-heterocyclic complexes of Rh and Ir. The direct reaction of the imidazolium salt with [IrCl(cod)]<sub>2</sub> provides ... View more
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