Hexaazamacrocyclic Nickel and Copper Complexes and their Reactivity with Tetracyanoquinodimethane

Dataset UNKNOWN
Ballester, Loreto; Gutiérrez, Angel; Perpiñán, M. Felisa; Sánchez, Ana E.; Fonari, Marina; Gdaniec, Maria;
(2007)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic062016h.s026, doi: 10.1021/ic062016h.s012
  • Subject: Molecular Biology | Biotechnology | crystal parameters | copper chloride | macrocyclic metal cations | copper atoms | 0.5 electrons | octahedral coordinative environment | metallomacrocyclic cations | crystal structures | hydrogen bonds | metal atom | chloride anions | amine macrocyclic groups | Hexaazamacrocyclic Nickel | crystal structure parameters | TCNQ salts | Cl 2 | nickel derivatives show | crystallization water molecules | nickel nitrate | TCNQ anions | Physiology | Medicine | dimeric dianions | dinuclear derivatives | reaction stoichiometries | Copper Complexes | form dimeric monoanions | Biochemistry | crystal structure | Cu 2 Cl 2 core
    • FOR: 29999 Physical Sciences not elsewhere classified | 110309 Infectious Diseases | 60506 Virology | 39999 Chemical Sciences not elsewhere classified

The hexaazamacrocycle 1,4,7,10,13,16-hexaazacyclooctadecane, [18]ane-N<sub>6</sub>, forms mono- and dinuclear derivatives with copper chloride depending on the reaction stoichiometries and times. The mononuclear derivative, [Cu([18]ane-N<sub>6</sub>)]Cl<sub>2</sub>·H... View more
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