Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes

Barrios-Landeros, Fabiola; Carrow, Brad P.; Hartwig, John F.;
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja900798s.s003, doi: 10.1021/ja900798s.s002, doi: 10.1021/ja900798s.s001
  • Subject: Molecular Biology | oxidative addition process | Developmental Biology | Sociology | Medicine | Computational Biology | Ligand Steric Properties | Space Science | Genetics | Pd | species | Biochemistry | dependence | steric properties | Biophysics | oxidative addition
    • FOR: 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The oxidative addition of PhX (X = I, Br, Cl) to the complexes Pd(P<sup><i>t</i></sup>Bu<sub>3</sub>)<sub>2</sub> (<b>1</b>), Pd(1-AdP<sup><i>t</i></sup>Bu<sub>2</sub>)<sub>2</sub> (<b>2</b>), Pd(CyP<sup><i>t</i></sup>Bu<sub>2</sub>)<sub>2</sub> (<b>3</b>), and Pd(PCy<s... View more
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