Dimerization of Phosphasilaferracycles:  Formation and Structures of Isomeric Fe2Si2P2 Six-Membered Metallacylcles

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Okazaki, Masaaki; Satoh, Kazuyuki; Jung, Kyeong A.; Tobita, Hiromi; Ogino, Hiroshi;
(2004)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/om034264g.s002, doi: 10.1021/om034264g.s001
  • Subject: Physiology | CO | 2 SiPPh 2 | Marine Biology | Cell Biology | Cp 2 Fe 2 | Biochemistry | isomeric mixture | Biophysics
    • FOR: 59999 Environmental Sciences not elsewhere classified | 29999 Physical Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Irradiation of Cp(CO)<sub>2</sub>FeSiMe<sub>2</sub>PPh<sub>2</sub> led to formation of an isomeric mixture of Cp<sub>2</sub>Fe<sub>2</sub>(CO)<sub>2</sub>[μ<sub>2</sub>-{κ<sup>2</sup>(<i>Si,P</i>)-Me<sub>2</sub>SiPPh<sub>2</sub>}]<sub>2</sub> through generation of Cp... View more
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