Biologically Relevant Phosphoranes:  Synthesis and Structural Characterization of Glucofuranose-Derived Phosphoranes with Penta- and Hexacoordination at Phosphorus

Timosheva, Natalya V.; Chandrasekaran, A.; Holmes, Robert R.;

Carbohydrate-based phosphoranes were synthesized by reacting the appropriate diphenol with phosphorus trichloride followed by the addition of chloralose to form <b>1 </b>and by the addition of isopropylidene-d-glucofuranose to form <b>2</b> and <b>3</b>. Phosphora... View more
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