Conjugation-Driven “Reverse Mars–van Krevelen”-Type Radical Mechanism for Low-Temperature C–O Bond Activation

Dataset UNKNOWN
Mironenko, Alexander V.; Vlachos, Dionisios G.;
(2016)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jacs.6b02871.s002, doi: 10.1021/jacs.6b02871.s003
  • Subject: multifunctional | surface | RuO 2 oxygen vacancies | scission | Medicine | bond | activity constraints | Cell Biology | Pd | catalyst | oxide | Rh | Biochemistry | Cancer | activation | relationship | mechanism | Biophysics | vacancy
    • FOR: 59999 Environmental Sciences not elsewhere classified | 110309 Infectious Diseases | 39999 Chemical Sciences not elsewhere classified

C–O bond activation on monofunctional catalysts (metals, carbides, and oxides) is challenging due to activity constraints imposed by energy scaling relationships. Yet, contrary to predictions, recently discovered multifunctional metal/metal oxide catalysts (... View more
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