Highly Stereo- and Regioselective Ni-Catalyzed Homoallylation of Aldimines with Conjugated Dienes Promoted by Diethylzinc

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Kimura, Masanari; Miyachi, Atsuko; Kojima, Keisuke; Tanaka, Shuji; Tamaru, Yoshinao;
(2004)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja0450354.s002, doi: 10.1021/ja0450354.s005, doi: 10.1021/ja0450354.s003, doi: 10.1021/ja0450354.s004
  • Subject: Molecular Biology | diethylzinc | Biotechnology | agent | diene | syn | regio | aldimine | Pharmacology | yield | arylamino | Regioselective | nickel catalysis | component | Cell Biology | aryl aldehydes | Conjugated Dienes Promoted | stereoselectivity | homoallylation products | Biochemistry | Stereo | Homoallylation | alkyl | aniline
    • FOR: 69999 Biological Sciences not elsewhere classified

Under the nickel catalysis, in one pot, diethylzinc serves as a reducing agent to connect the three components of 1,3-dienes, alkyl or aryl aldehydes, and anilines to furnish 3-substituted 3,5-<i>syn</i>-5-(arylamino)pent-1-enes <b>1</b>, the homoallylation products of ... View more
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