Formazanate Ligands as Structurally Versatile, Redox-Active Analogues of β‑Diketiminates in Zinc Chemistry

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Chang, Mu-Chieh; Roewen, Peter; Travieso-Puente, Raquel; Lutz, Martin; Otten, Edwin;
(2015)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic5025873.s006, doi: 10.1021/ic5025873.s005, doi: 10.1021/ic5025873.s004, doi: 10.1021/ic5025873.s003, doi: 10.1021/ic5025873.s002
  • Subject: formazanate framework | metal center | zinc center | formazanate ligand forms | Pharmacology | Zinc ChemistryA range | ligand backbone | Biophysics | NAr substituents | formazanate ligands | UV | hypsochromic shifts | ligand substitution pattern | N atom | Medicine | terminal N atoms | L 2Zn forms | NNCNN ligand backbone | L 2Zn | redox potentials | cyclic voltammetry | L 2Zn compounds | Biochemistry | Structurally Versatile | NMes group | absorption spectra | compounds show
    • FOR: 29999 Physical Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

A range of tetrahedral bis­(formazanate)zinc complexes with different steric and electronic properties of the formazanate ligands were synthesized. The solid-state structures for several of these were determined by X-ray crystallography, which showed that co... View more
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