Single Crystal to Single Crystal Polymerization of a Self-Assembled Diacetylene Macrocycle Affords Columnar Polydiacetylenes

Dataset UNKNOWN
Xu, Weiwei L.; Smith, Mark D.; Krause, Jeanette A.; Greytak, Andrew B.; Ma, Shuguo; Read, Cory M.; Shimizu, Linda S.;
(2014)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/cg401380a.s002, doi: 10.1021/cg401380a.s003, doi: 10.1021/cg401380a.s004, doi: 10.1021/cg401380a.s005
  • Subject: Molecular Biology | Biotechnology | Plant Biology | Single Crystal | amide hydrogen bonds | Biophysics | Immunology | PDA crystals | Single Crystal Polymerization | water tetramers | 2 vapor | Microbiology | PDA chains | Å. | PDA structure | Computational Biology | 2 D sheet structure | Biochemistry | crystal forms | columnar assembly | bulk PDA powder | property control | 2O | PDA nanotube
    • FOR: 29999 Physical Sciences not elsewhere classified | 60506 Virology | 39999 Chemical Sciences not elsewhere classified

This manuscript describes a single-crystal-to-single-crystal polymerization of the dihydrate of diacetylene <b>1</b> (<b>1</b>·2H<sub>2</sub>O) to give an unusual polydiacetylene (PDA) structure that consists of aligned nanotubes, with each covalently bonded na... View more
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