Versatile Coordination of Cyclopentadienyl-Arene Ligands and Its Role in Titanium-Catalyzed Ethylene Trimerization

Otten, Edwin; Batinas, Aurora A.; Meetsma, Auke; Hessen, Bart;

Cationic titanium(IV) complexes with <i>ansa</i>-(η<sup>5</sup>-cyclopentadienyl,η<sup>6</sup>-arene) ligands were synthesized and characterized by X-ray crystallography. The strength of the metal−arene interaction in these systems was studied by variable-temperature NM... View more
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