Enantioselective Rh-Catalyzed Carboacylation of CN Bonds via C–C Activation of Benzocyclobutenones

Deng, Lin; Xu, Tao; Li, Hongbo; Dong, Guangbin;

Herein we describe the first enantioselective Rh-catalyzed carboacylation of oximes (imines) via C–C activation. In this transformation, the benzocyclobutenone C1–C2 bond is selectively activated by a low valent rhodium catalyst and subsequently the resultin... View more
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