Anion-Tunable Configuration Isomerism and Magnetic Coupling in a Tetranuclear Discrete, One-Dimensional (1D) Chiral Chain and 1D-Decker Copper(II) Complexes of a Carbohydrazine Derivative

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Huang, Wei; Jin, Yuchao; Wu, Dayu; Wu, Genhua;
(2014)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic4014027.s007, doi: 10.1021/ic4014027.s005, doi: 10.1021/ic4014027.s006
  • Subject: room temperature | Carbohydrazine DerivativeThe reactions | compound 1 | 1 D chiral chain | 1 D uniform chain | ppcd ligand | cm | subunit | trinuclear | configuration isomerism | Cu | Cell Biology | Biochemistry | Chiral Chain | antiferromagnetic | Biophysics | Tetranuclear Discrete | conformation isomerism | coordination mode
    • FOR: 29999 Physical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The reactions of ligand <i>N</i>′-[(pyridin-2-yl)­methylene]­pyrazine-2-carbohydrazide (ppcd) with different copper salts (<b>1</b>, acetate; <b>2</b>, perchlorate; <b>3</b>, sulfate) in MeOH could afford one acetate-bridge tetranuclear discrete [Cu<sub>2</sub>(pp... View more
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