Metallaboratranes:  Tris(methimazolyl)borane Complexes of Rhodium(I)

Crossley, Ian R.; Hill, Anthony F.; Willis, Anthony C.;

The syntheses and reactivity of the first rhodaboratranes, [RhX(PPh<sub>3</sub>){B(mt)<sub>3</sub>}] (X = Cl, H) and [Rh(η<sup>4</sup>-C<sub>8</sub>H<sub>12</sub>){B(mt)<sub>3</sub>}]Cl, are described in detail together with preliminary investigations of the mechanistic... View more
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