Reaction of Elemental Sulfur with a Copper(I) Complex Forming a trans-μ-1,2 End-On Disulfide Complex:  New Directions in Copper−Sulfur Chemistry

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Helton, Matthew E.; Chen, Peng; Paul, Partha P.; Tyeklár, Zoltán; Sommer, Roger D.; Zakharov, Lev N.; Rheingold, Arnold L.; Solomon, Edward I.; Karlin, Kenneth D.;
(2003)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja027574j.s003, doi: 10.1021/ja027574j.s002
  • Subject: Forming | Plant Biology | S 8 | Elemental Sulfur | Genetics | Complex | sulfur | TMPA | Biophysics | tran | centrosymmetric disulfide | New | Disulfide | CH | length | Å. | CN | bond | Cu | Directions | Biochemistry | Cancer
    • FOR: 59999 Environmental Sciences not elsewhere classified | 29999 Physical Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Elemental sulfur (S<sub>8</sub>) was found to react with [(TMPA)Cu<sup>I</sup>(CH<sub>3</sub>CN)]<sup>+</sup> to form the <i>trans</i>-μ-1,2 end-on disulfide complex [(TMPA)Cu−S−S−Cu(TMPA)]<sup>2+</sup>. The X-ray structure of this centrosymmetric disulfide complex show... View more
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