Chiral Phosphoric Acid-Catalyzed Oxidative Kinetic Resolution of Indolines Based on Transfer Hydrogenation to Imines

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Saito, Kodai; Shibata, Yukihiro; Yamanaka, Masahiro; Akiyama, Takahiko;
(2016)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja406004q.s004, doi: 10.1021/ja406004q.s003, doi: 10.1021/ja406004q.s006, doi: 10.1021/ja406004q.s005
  • Subject: Molecular Biology | Biotechnology | indoline derivatives | Microbiology | Plant Biology | Transfer Hydrogenation | chiral phosphoric acid catalyst | IminesThe oxidative | hydrogen transfer | Computational Biology | Evolutionary Biology | racemic alkyl | Biochemistry | Cancer
    • FOR: 59999 Environmental Sciences not elsewhere classified | 110309 Infectious Diseases | 69999 Biological Sciences not elsewhere classified | 60506 Virology | 39999 Chemical Sciences not elsewhere classified

The oxidative kinetic resolution of 2-substituted indoline derivatives was achieved by hydrogen transfer to imines by means of a chiral phosphoric acid catalyst. The oxidative kinetic resolution was applicable to racemic alkyl- or aryl-substituted indolines,... View more
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