Tuning Intrinsic and Extrinsic Proton Conduction in Metal–Organic Frameworks by the Lanthanide Contraction

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Wong, Norman E.; Ramaswamy, Padmini; Lee, Andrew S.; Gelfand, Benjamin S.; Bladek, Kamila J.; Taylor, Jared M.; Spasyuk, Denis M.; K. H. Shimizu, George;
(2017)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jacs.7b07987.s002, doi: 10.1021/jacs.7b07987.s003
  • Subject: Molecular Biology | Biotechnology | Ln | MOF | Plant Biology | Single crystal structures | lattice strain effects | hydrogen phosphonate groups | Ecology | Proton conductivity measurements | member | Biophysics | Extrinsic Proton Conduction | Pr complexes | Scanning electron microscopy | proton transfer pathway | Microbiology | PCMOF | activation energy pathway | lanthanide | Cell Biology | unit cell parameters | La | series | Biochemistry | Cancer | unit cell dimensions
    • FOR: 59999 Environmental Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Seven isomorphous lanthanide metal–organic frameworks in the PCMOF-5 family, [Ln­(H<sub>5</sub>L)­(H<sub>2</sub>O)<i>n</i>]­(H<sub>2</sub>O) (L = 1,2,4,5-tetrakis­(phosphonomethyl)­benzene, Ln = La, Ce, Pr, Nd, Sm, Eu, Gd) have been synthesized and characterize... View more
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