Convenient Solution Route To Alkylated Pentalene Ligands: New Metal Monoalkylpentalenyl Complexes

Dataset UNKNOWN
Jones, Simon C.; Roussel, Paul; Hascall, Tony; O'Hare, Dermot;
(2006)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/om0507326.s004, doi: 10.1021/om0507326.s003, doi: 10.1021/om0507326.s002, doi: 10.1021/om0507326.s001
  • Subject: Molecular Biology | Biotechnology | Plant Biology | pentalene ligands | dihydropentalene | Pharmacology | Biophysics | monodeprotonation | deprotonation | isomers | dinuclear Mn organometallics | Microbiology | dibromo | CO | Convenient Solution Route | pentalenyl salts Li 2 | alkylated pentalene ligands | Re | Biochemistry | C 8 H 5 R | Tl | DME | rearrangement | dibromobicyclo
    • FOR: 29999 Physical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Carbene-induced rearrangement of 8,8-dibromobicyclo[5.1.0]octa-2,4-dienes and subsequent in situ deprotonation of the dihydropentalenes formed represents a straightforward and versatile solution route to pentalene ligands for use in organometallic chemistry. We re... View more
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