Development of Catalysts for the Stereoselective Hydrogenation of α,β-Unsaturated Ketones

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Maurer, Frauke; Huch, Volker; Ullrich, Angelika; Kazmaier, Uli;
(2012)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/jo300246c.s003, doi: 10.1021/jo300246c.s002, doi: 10.1021/jo300246c.s001
  • Subject: Biotechnology | KetonesIridium | cyclic substrates | hydrogenation | Unsaturated | ketone | Space Science | Ecology | Evolutionary Biology | Stereoselective Hydrogenation | complex | ee | Linear | arylated | phosphinitoxazoline | Cell Biology | hydrogenated | catalyst | Biochemistry | selectivitie | Cancer
    • FOR: 59999 Environmental Sciences not elsewhere classified | 29999 Physical Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

Iridium phosphinitoxazoline complexes were found to be new efficient catalysts for the asymmetric hydrogenation of arylated α,β-unsaturated ketones. Linear as well as cyclic substrates are hydrogenated with similar success, giving selectivities of up to 99.7... View more
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