Hydroboration and Hydrogenation of an Osmium–Carbon Triple Bond: Osmium Chemistry of a Bis-σ-Borane

Dataset UNKNOWN
Buil, Marı́a L.; J. F. Cardo, Juan; Esteruelas, Miguel A.; Fernández, Israel; Oñate, Enrique;
(2015)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/om501274x.s001, doi: 10.1021/om501274x.s003
  • Subject: Biotechnology | hydroxo group | 4 atm | Hydroboration | OsH | bi | pinacolborane | Plant Biology | hydrogenation | Bis | CF 3SO | Genetics | Evolutionary Biology | reagent | Pharmacology | yield | chloride ligand | Biophysics | OTf | Osmium Chemistry | Neuroscience | Developmental Biology | Physiology | Medicine | IPr | arene compound | bond | hydroboration products | Cell Biology | Na | Triple | Biochemistry | Cancer | H 2 | HBPin | toluene | OsHCl
    • FOR: 59999 Environmental Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The complex [OsHCl­(CPh)­(IPr)­(P<sup><i>i</i></sup>Pr<sub>3</sub>)]­OTf (<b>1</b>; IPr = 1,3-bis­(2,6-diisopropylphenyl)­imidazolylidene, OTf = CF<sub>3</sub>SO<sub>3</sub>) replaces the chloride ligand with a hydroxo group to give [OsH­(OH)­(CPh)­(IPr)­(P<s... View more
Share - Bookmark

  • Download from
    figshare via figshare (Dataset, 2015)
  • Cite this research data