Synthesis and Oxidative Reactivity of 2,2′-Pyridylpyrrolide Complexes of Ni(II)

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Tsvetkov, Nikolay P.; Chen, Chun-Hsing; Andino, José G.; Lord, Richard L.; Pink, Maren; Buell, René W.; Caulton, Kenneth G.;
(2013)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic4011746.s003, doi: 10.1021/ic4011746.s002, doi: 10.1021/ic4011746.s005, doi: 10.1021/ic4011746.s004
  • Subject: cyclic voltammograms | Biotechnology | H 2O tetrahydrofuran | cyclic voltammetry studies | Varied substituents | divalent nickel complexed | pyrrolide ring hydrogen | show electroactivity | Br 2 | ligand | oxidative direction | latter effects electrophilic | L 2 case | CF 3 | mass spectrometry | Biophysics | Lewis acidity | pyrrolide groups | CO | bis adducts | Cell Biology | THF | CV | theory calculations show | Oxidative Reactivity | Biochemistry | Ni | frontier orbitals
    • FOR: 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified
    acm: TheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITY

Synthesis and characterization of divalent nickel complexed by 2-pyridylpyrrolide bidentate ligands are reported, as possible precursors to complexes with redox active ligands. Varied substituents on the pyrrolide, two CF<sub>3</sub> (L<sup>2</sup>), two <su... View more
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