Effects of the Intramolecular NH···S Hydrogen Bond in Mononuclear Platinum(II) and Palladium(II) Complexes with 2,2‘-Bipyridine and Benzenethiol Derivatives

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Kato, Masahiro; Okamura, Taka-aki; Yamamoto, Hitoshi; Ueyama, Norikazu;
(2005)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ic0490167.s002, doi: 10.1021/ic0490167.s001
  • Subject: UV | Biotechnology | Pt | Developmental Biology | BuNHCOC 6 H 4 | electrochemical properties | amide NH group | CCONHC | bond | sulfur atom | 1 H NMR spectra | Benzenethiol Derivatives | 42 nm | IR spectra | Biochemistry | complex | 1 H NMR | Biophysics
    • FOR: 29999 Physical Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

A series of complexes, [M(bpy)(SAr)<sub>2</sub>] (M = platinum(II) or palladium(II), bpy = 2,2‘-bipyridine, SAr = 2- or 4-(acylamino)benzenethiolate, or 2-(alkylcarbamoyl)benzenethiolate), were synthesized and characterized on the basis of <sup>1</sup>H NMR, IR, a... View more
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