Alkene–Carbene Isomerization induced by Borane: Access to an Asymmetrical Diborene

Lu, Wei; Li, Yongxin; Ganguly, Rakesh; Kinjo, Rei;

A 2,3-dihydro-1<i>H</i>-1,2-azaborole derivative <b>2</b> was converted to a cyclic (alkyl) (amino)­carbene (cAAC) via 1,2-hydrogen migration triggered by boranes to afford cAAC-borane adducts. This procedure allowed us to develop an asymmetrical diborene cA... View more
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