trans-Mutation at Gold(III): A Mechanistic Study of a Catalytic Acetylene Functionalization via a Double Insertion Pathway

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Holmsen, Marte Sofie Martinsen; Nova, Ainara; Balcells, David; Langseth, Eirin; Øien-Ødegaard, Sigurd; Heyn, Richard H.; Tilset, Mats; Laurenczy, Gábor;
(2017)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/acscatal.7b01364.s003, doi: 10.1021/acscatal.7b01364.s002
  • Subject: Catalytic Acetylene Functionalization | CH | Double Insertion Pathway | site trans | vinyl group | Evolutionary Biology | DFT | OCOCF | Biochemistry | coordination-nucleophilic attack-protolysis sequence | tpy | Biophysics
    • FOR: 59999 Environmental Sciences not elsewhere classified | 110309 Infectious Diseases | 69999 Biological Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The Au­(III) complex Au­(tpy)­(OAc<sup>F</sup>)<sub>2</sub> (OAc<sup>F</sup> = OCOCF<sub>3</sub>; tpy = 2-(<i>p</i>-tolyl)­pyridine) catalyzes the <i>anti</i> addition of trifluoroacetic acid (HOAc<sup>F</sup>) to acetylene to furnish vinyl trifluoroacetate. ... View more
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