Molybdenum Carbonyl Complexes in the Solvent-Free Catalytic Hydrogenation of Ketones

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Kimmich, Barbara F. M.; Fagan, Paul J.; Hauptman, Elisabeth; Marshall, William J.; Bullock, R. Morris;
(2005)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/om050564h.s001, doi: 10.1021/om050564h.s002, doi: 10.1021/om050564h.s003
  • Subject: Biotechnology | metal triflate complexes | C 4 H 5 | Physiology | Ph 3 C | C 5 H 4 | t Bu | 2 PR 2 | HMo | HW | Molybdenum Carbonyl Complexes | Cell Biology | catalyst | Biochemistry | Pharmacology | CH 2 | Cancer | Biophysics
    • FOR: 39999 Chemical Sciences not elsewhere classified

The heterodifunctional ligand Li[η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>(CH<sub>2</sub>)<sub>2</sub>PR<sub>2</sub>] (R = Ph, Cy, and <sup>t</sup>Bu) reacts with Mo(CO)<sub>3</sub>(diglyme) to give the molybdenum anion complex Li{Mo(CO)<sub>3</sub>[η<sup>5</sup>-C<su... View more
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