research data . Dataset . 2016

Bonding, Hyperfine Interactions, and Lattice Dynamics of Cationic and Neutral Ferrocenyl-Substituted Allylic and Cumulenic Compounds

Herber, Rolfe H.; Bildstein, Benno; Denifl, Peter; Schottenberger, Herwig;
  • Published: 01 Jan 2016
  • Publisher: Figshare
Abstract
The synthesis and spectroscopic characterization (by mass, UV−visible, IR, NMR and <sup>57</sup>Fe Mössbauer spectroscopy) of three new compounds related to seven recently published ferrocenyl-substituted allylic and cumulenic compounds are reported and have made it possible to effect a systematic evaluation of the parameters extractable from temperature-dependent γ ray resonance studies. For the neutral species, the hyperfine parameters (IS and QS) of the σ-bonded ferrocenyl groups are insensitive to the structural details of the allylic or cumulenic carbon framework. The temperature dependence of the recoil-free fraction is ...
Subjects
free text keywords: Biotechnology, parameters extractable, M össbauer data, NMR, Evolutionary Biology, carbocationic complexes, Pharmacology, 57 Fe M össbauer spectroscopy, ferrocenyl groups, Lattice Dynamics, equivalent termini, Biophysics, UV, QS, Cumulenic Compounds, IR, Medicine, 10 complexes, Hyperfine Interactions, fraction, inequivalent moieties, Biochemistry, spectroscopic characterization, temperature dependence, racemic nature, allylic, pm, iron sites, cumulenic carbon framework, 29999 Physical Sciences not elsewhere classified, 39999 Chemical Sciences not elsewhere classified
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Dataset . 2016
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research data . Dataset . 2016

Bonding, Hyperfine Interactions, and Lattice Dynamics of Cationic and Neutral Ferrocenyl-Substituted Allylic and Cumulenic Compounds

Herber, Rolfe H.; Bildstein, Benno; Denifl, Peter; Schottenberger, Herwig;