Scopariusicides, Novel Unsymmetrical Cyclobutanes: Structural Elucidation and Concise Synthesis by a Combination of Intermolecular [2 + 2] Cycloaddition and C–H Functionalization

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Zhou, Min; Li, Xing-Ren; Tang, Jian-Wei; Liu, Yang; Li, Xiao-Nian; Wu, Bin; Qin, Hong-Bo; Du, Xue; Li, Li-Mei; Wang, Wei-Guang; Pu, Jian-Xin; Sun, Han-Dong;
(2015)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/acs.orglett.5b03079.s002, doi: 10.1021/acs.orglett.5b03079.s006, doi: 10.1021/acs.orglett.5b03079.s005, doi: 10.1021/acs.orglett.5b03079.s004, doi: 10.1021/acs.orglett.5b03079.s003
  • Subject: Molecular Biology | access | Intermolecular | Concise Synthesis | synergistically | Ecology | stereocontrolled synthesis | unsymmetrical cyclobutane derivatives | Biophysics | sp | Combination | Structural Elucidation | analogue | Isodon scoparius | phytochemical investigation | bond | arylation | photocycloaddition | stereocenter | Cycloaddition | material | Biochemistry | unsymmetrical cyclobutane core | FunctionalizationScopariusicide | Novel Unsymmetrical Cyclobutanes | diterpenoid | scopariusicide
    • FOR: 59999 Environmental Sciences not elsewhere classified | 69999 Biological Sciences not elsewhere classified | 60506 Virology | 39999 Chemical Sciences not elsewhere classified

Scopariusicides A (<b>1</b>) and B (<b>2</b>), two novel immunosuppressive unsymmetrical cyclobutane derivatives, were isolated from the aerial parts of <i>Isodon scoparius</i>. Moreover, based on the results of phytochemical investigation, a concise stereoc... View more
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