Bimetallic Coordination Insertion Polymerization of Unprotected Polar Monomers: Copolymerization of Amino Olefins and Ethylene by Dinickel Bisphenoxyiminato Catalysts

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Radlauer, Madalyn R.; Buckley, Aya K.; Henling, Lawrence M.; Agapie, Theodor;
(2016)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja4004816.s003, doi: 10.1021/ja4004816.s002
  • Subject: incorporation | Biotechnology | reactivity | bimetallic strategy | amines | syn | copolymerized | ethylene | atropisomer | Amino Olefins | presence | Biophysics | heteroatom group | Copolymerization | Bimetallic Coordination Insertion Polymerization | monomer | olefin | Medicine | olefins | phosphine scavenger | catalyst structure | insertion polymerization | Dinickel Bisphenoxyiminato CatalystsDinickel bisphenoxyiminato complexes | Biochemistry | Ni | Unprotected Polar Monomers
    • FOR: 39999 Chemical Sciences not elsewhere classified

Dinickel bisphenoxyiminato complexes based on highly substituted <i>p</i>- and <i>m</i>-terphenyl backbones were synthesized, and the corresponding atropisomers were isolated. In the presence of a phosphine scavenger, Ni­(COD)<sub>2</sub>, the phosphine-ligated... View more
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