On the Mechanism of Palladium-Catalyzed Aromatic C−H Oxidation

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Powers, David C.; Xiao, Daphne Y.; A. L. Geibel, Matthias; Ritter, Tobias;
(2010)
  • Publisher: Figshare
  • Related identifiers: doi: 10.1021/ja1054274.s003, doi: 10.1021/ja1054274.s002
  • Subject: catalysi | acetate ions | Computational Biology | Space Science | dinuclear | Pd | chlorination proceeds | bimetallic oxidation | Biochemistry | reaction kinetics analysis | Biophysics
    • FOR: 59999 Environmental Sciences not elsewhere classified | 39999 Chemical Sciences not elsewhere classified

The mechanism of Pd-catalyzed aromatic C−H oxidation chemistry continues to be vigorously discussed. Historically, Pd(II)/Pd(IV) catalysis cycles have been proposed. Herein, we present a detailed study of Pd(OAc)<sub>2</sub>-catalyzed aromatic C−H chlorination and propo... View more
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