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We exploit the data from five seismic transects deployed across the Pyrenees to characterize the deep architecture of this collisional orogen. We map the main seismic interfaces beneath each transect by depth migration of P-to-S converted phases. The migrated sections, combined with the results of recent tomographic studies and with maps of Bouguer and isostatic anomalies, provide a coherent crustal-scale picture of the belt. In the Western Pyrenees, beneath the North Pyrenean Zone, a continuous band of high density/velocity material is found at a very shallow level (~10 km) beneath the Mauleon basin and near Saint-Gaudens. In the Western Pyrenees, we also find evidence for northward continental subduction of Iberian crust, down to 50–70 km depth. In the Eastern Pyrenees, these main structural features are not observed. The boundary between these two domains is near longitude 1.3 °E, where geological field studies document a major change in the structure of the Cretaceous rift system, and possibly a shift of its polarity, suggesting that the deep orogenic architecture of the Pyrenees is largely controlled by structural inheritance. The PYROPE (Pyrenean Observational Portable Experiment) project was supported by the Agence Nationale de la Recherche (ANR) Blanc Programme (project PYROPE, ANR-09- BLAN-0229). We also acknowledge SISMOB, the French seismic mobile pool (a component of the RESIF consortium - http://seismology.resif.fr), for providing us with the seismological instrumentation for the temporary deployments. Field work has been also partially funded by the Spanish Ministry of Economy and Competitiveness through Project MISTERIOS (CGL2013-48601-C2-2-R). Peer reviewed

FAIR principles have become reference criteria for promoting and evaluating openness of scientific data and for improving datasets Findability, Accessibility, Interoperability, and Reusability. This also applies to Research Infrastructures (RIs) in the solid Earth domain committed to provide access to seismological data, ground deformations inferred from terrestrial, and satellite observations, geological maps, and laboratory experiments. Such RIs have been indeed committed for a long time, well before the appearance of FAIR principles, to engage scientific communities involved in data collection, standardization, and quality control as well as in implementing metadata and services for qualification, storage and accessibility. By addressing open science and managing scientific data, they are working to adopt FAIR principles, thus having the onerous task of turning these principles into practices. In this work we argue that although FAIR principles have the merit of creating a common background of knowledge to engage communities in providing data in a standard way thus easing interoperability and data sharing, in order to make the adoption of FAIR principles less onerous there is an urgent need of clear models, reference architectures and technical guidelines which can support RI implementers in the realization of FAIR data provision systems. We therefore discuss the state of the art of FAIR principles ecosystem and open new perspectives by discussing a four-stages roadmap that reorganizes FAIR principles in a way that better fits to the approach of RI implementers, and a FAIR adoption process that relates FAIR principles to technologies for their implementation.

Abstract We present a joint exploitation of space-borne and ground-based Synthetic Aperture Radar Interferometry (InSAR) and Multi Temporal (MT) InSAR measurements for investigating the Stromboli volcano (Italy) deformation phenomena. In particular, we focus our analysis on three periods: a) the time interval following the 2014 flank eruption, b) the July–August 2019 eruption and c) the following post-eruptive phase. To do this, we take advantage from an unprecedented set of space-borne and ground-based SAR data collected from April 2015 up to November 2019 along two (one ascending and one descending) Sentinel-1 (S-1) tracks, as well as, in the same period, by two ground-based systems installed along the Sciara del Fuoco northern rim. Such data availability permitted us to first characterize the volcano long-term 3D deformation behavior of the pre-eruptive period (April 2015–June 2019), by jointly inverting the space-borne and ground-based InSAR measurements. Then, the GB-SAR measurements allowed us to investigate the sin-eruptive time span (3rd July 2019 – 30th August 2019) which revealed rapid deformation episodes (e.g. more than 30 mm/h just 2 min before the 3rd July 2019 explosion) associated with the eruptive activity, that cannot be detected with the weekly S-1 temporal sampling. Finally, the S-1 measurements permitted to better constrain the post 2019 eruption deformations (31st August 2019 – 5th November 2019), which are mainly located outside the GB-SAR sensed area. The presented results demonstrate the effectiveness of the joint exploitation of the InSAR measurements obtained through satellite and terrestrial SAR systems, highlighting their strong complementarity to map and interpret the deformation phenomena affecting volcanic areas.

During the last decades, the availability of Synthetic Aperture Radar (SAR) satellite missions, such as the ERS-1/2 and ENVISAT ones operating at C-band who have worked since 1992 to 2011, as well as the X-band COSMOSkyMed and TerraSAR-X constellations, up to the brand new Sentinel-1 mission, have strongly contributed to SAR data diffusion and popularity in the generation of different studies at different scales and in different research fields. One of the most popular SAR technique is the one referred to as Differential SAR Interferometry (DInSAR), which allows measuring with centimeter accuracy the Earth's surface deformation entity related to both natural and man-made hazards. Nowadays, with the increasing of SAR data availability provided by Sentinel-1 constellation of Copernicus European Program, which is composed by two twin satellites operating in C-band since 2014 and 2016, with a repeat pass of 6 days and with a global (i.e. worldwide) data acquisition policy, the SAR EO scenario is becoming more and more operational, thus mainly providing support for natural hazards monitoring. This allows, in theory, and disposing of sufficient computing power, the EO community to monitor, for instance, the deformation of every volcano or to obtain co-seismic displacement maps in a short time frame and anywhere in the world. Accordingly, in this work, we present a fully automatic and fast processing service for the generation of co-seismic displacement maps by using Sentinel-1 data. The implemented system is completely unsupervised and is triggered by the all significant (i.e. larger than a defined magnitude) seismic event registered by the online catalog as those provided by the United States Geological Survey (USGS) and the National Institute of Geophysics and Volcanology of Italy (INGV). The service has been specifically designed to operate for Civil Protection purposes. The generated DInSAR measurements are made available to the geoscience community through the EPOS Research Infrastructure and they will contribute to the creation of a global database of co-seismic displacement maps. Finally, it is worth noting that the developed system relies on widely common IT methods and protocols and is not specifically tied to a defined computing architecture, thus implying its portability, in view also of the European Commission Data and Information Access Services (DIAS) where satellite data (mainly Sentinel) and processing facilities are co-located to reduce the data transfer time during their processing.

With permission from Alemayehu, A.B., McCormick, L.J.M., Gagnon, K.J., Borisov, S.M. & Ghosh, A. (2018). Stable Platinum(IV) Corroles: Synthesis, Molecular Structure, and Room-Temperature Near-IR Phosphorescence. ACS Omega, 3(8), 9360-9368. Copyright 2018 American Chemical Society. Source at https://doi.org/10.1021/acsomega.8b01149. A series of stable Pt(IV) corrole complexes with the general formula PtIV[TpXPC](m/p-C6H4CN)(py), where TpXPC3– is the trianion of a tris(p-X-phenyl)corrole and X = CF3, H, and CH3, has been synthesized, affording key physicochemical data on a rare and elusive class of metallocorroles. Single-crystal X-ray structures of two of the complexes revealed very short equatorial Pt–N distances of 1.94–1.97 Å, an axial Pt–C distance of ∼2.03 Å, and an axial Pt–N distance of ∼2.22 Å. The complexes exhibit Soret maxima at ∼430 nm, which are essentially independent of the meso-aryl para substituents, and strong Q bands with the most intense peak at 595–599 nm. The substituent-independent Soret maxima are consistent with an innocent PtIV–corrole3– description for the complexes. The low reduction potentials (−1.45 ± 0.08 V vs saturated calomel reference electrode) also support a highly stable Pt(IV) ground state as opposed to a noninnocent corrole•2– description. The reductions, however, are irreversible, which suggests that they involve concomitant cleavage of the Pt–aryl bond. Unlike Pt(IV) porphyrins, two of the complexes, PtIV[TpXPC](m-C6H4CN)(py) (X = CF3 and CH3), were found to exhibit room-temperature near-IR phosphorescence with emission maxima at 813 and 826 nm, respectively. The quantum yield of ∼0.3% is comparable to those observed for six-coordinate Ir(III) corroles.

Virtual Research Environments (VREs), also known as science gateways or virtual laboratories, assist researchers in data science by integrating tools for data discovery, data retrieval, workflow management and researcher collaboration, often coupled with a specific computing infrastructure. Recently, the push for better open data science has led to the creation of a variety of dedicated research infrastructures (RIs) that gather data and provide services to different research communities, all of which can be used independently of any specific VRE. There is therefore a need for generic VREs that can be coupled with the resources of many different RIs simultaneously, easily customised to the needs of specific communities. The resource metadata produced by these RIs rarely all adhere to any one standard or vocabulary however, making it difficult to search and discover resources independently of their providers without some translation into a common framework. Cross-RI search can be expedited by using mapping services that harvest RI-published metadata to build unified resource catalogues, but the development and operation of such services pose a number of challenges. In this paper, we discuss some of these challenges and look specifically at the VRE4EIC Metadata Portal, which uses X3ML mappings to build a single catalogue for describing data products and other resources provided by multiple RIs. The Metadata Portal was built in accordance to the e-VRE Reference Architecture, a microservice-based architecture for generic modular VREs, and uses the CERIF standard to structure its catalogued metadata. We consider the extent to which it addresses the challenges of cross-RI search, particularly in the environmental and earth science domain, and how it can be further augmented, for example to take advantage of linked vocabularies to provide more intelligent semantic search across multiple domains of discourse.

AbstractThe availability of GPS survey data spanning 22 years, along with several independent velocity solutions including up to 16 years of permanent GPS data, presents a unique opportunity to search for persistent (and thus reliable) deformation patterns in the Western Alps, which in turn allow a reinterpretation of the active tectonics of this region. While GPS velocities are still too uncertain to be interpreted on an individual basis, the analysis of range‐perpendicular GPS velocity profiles clearly highlights zones of extension in the center of the belt (15.3 to 3.1 nanostrain/year from north to south), with shortening in the forelands. The contrasting geodetic deformation pattern is coherent with earthquake focal mechanisms and related strain/stress patterns over the entire Western Alps. The GPS results finally provide a reliable and robust quantification of the regional strain rates. The observed vertical motions of 2.0 to 0.5 mm/year of uplift from north to south in the core of the Western Alps is interpreted to result from buoyancy forces related to postglacial rebound, erosional unloading, and/or viscosity anomalies in the crustal and lithospheric root. Spatial decorrelation between vertical and horizontal (seismicity related) deformation calls for a combination of processes to explain the complex present‐day dynamics of the Western Alps.

AbstractLate Miocene to Pleistocene volcanism within the Vardar zone (North Macedonia) covers a large area, has a wide range in composition, and is largely connected to the tectonic evolution of the South Balkan extensional system, the northern part of the Aegean extensional regime. The onset of the scattered potassic to ultrapotassic volcanism south from the Scutari-Peć transverse zone occurred at ca. 8.0 Ma based on this study. Here, we focused on three volcanic centers located on deep structures or thrust faults along the western part of the Vardar zone, for which there is none to very little geochronological and geochemical data available. Pakoševo and Debrište localities are represented as small remnants of lava flows cropping out at the southern edge of Skopje basin and at the western edge of Tikveš basin, respectively. Šumovit Greben center is considered as part of the Kožuf-Voras volcanic system, and it is located on its westernmost side, at the southern edge of Mariovo basin, which is largely composed of volcaniclastic sediments. We present new eruption ages applying the unspiked Cassignol-Gillot K–Ar technique on groundmass, as well as petrological and geochemical data, supplemented with Sr and Nd isotopes to complement and better understand the Neogene-Pleistocene volcanism in the region. Eruption ages on these rocks interlayered between sedimentary formations allow to better constrain the evolution of those sedimentary basins. Rocks from the three volcanic centers belong to the high-K calc-alkaline–shoshonitic series based on their elevated K content. The oldest center amongst these three localities, as well as other Late Miocene centers within the region, is the trachyandesitic Debrište, which formed at ca. 8.0 Ma, and exhibits the highest Nd and lowest Sr isotopic ratios (0.512441–0.512535 and 0.706759–0.706753, respectively). The basaltic trachyandesite Pakoševo center formed at ca. 3.8 Ma and its Nd and Sr isotopic ratios (0.512260 and 0.709593, respectively) bear the strongest signature of crustal contamination. The rhyolitic Šumovit Greben center is a composite volcanic structure formed at ca. 3.0–2.7 Ma. Its youngest eruption unit has a slightly higher Nd and lower Sr isotopic ratios (0.512382 and 0.709208, respectively) representing a magma with a lesser extent of crustal assimilation than the other samples from this center. The overall trend through time in the Sr and Nd isotopic ratios of the Late Miocene to Pleistocene mafic volcanic centers in the region implies an increasing rate of metasomatism of the lithospheric mantle.