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Here, nitrogen doped molybdenum disulfide quantum dots (N-MoS2 QDs) are fabricated by making use of the pulsed laser ablation (PLA) process in liquid nitrogen (LN2) as a dopant agent. In fact, LN2 contributes the rapid condensation of the plasma plume to form MoS2 QDs, optimizing the conditions for the synthesis of N-doped MoS2 with p-type property. The structural/optical features of the synthesized products are studied using transmission electron microscopy (TEM), absorption spectroscopy, photoluminescence (PL) spectroscopy techniques, and X-ray photoelectron spectroscopy (XPS). The TEM image shows the creation of MoS2 QDs with 5.5 nm average size. UV-vis and PL spectroscopy confirm the formation of N-MoS2 QDs according to the dominant peaks. The Tuck plot gives a direct band-gap of 4.34 eV for MoS2 QDs. Furthermore, XPS spectroscopy reveals Mo-N bonding, indicating nitrogen doping as evidence of p-type MoS2 QDs. Thus, PLA provides a single-stage way to the clean and green synthesis of the MoS2 QDs suspension without a need for high vacuum devices and additional chemical components. Regarding the pristine MoS2, the N-MoS2 QDs benefit from a low overpotential of −0.35 V at −10 mA/cm2 per µg alongside a low Tafel slope of 300 mV/dec. Subsequently, the lower Rct value of N-MoS2 QDs verifies the enhancement of the charge transfer kinetics mainly due to the elevated electronic conductivity. Furthermore, the quasi-rectangular cyclic voltammetry (CV) as well as the larger current window demonstrate a notable electrocatalytic activity. The former is based on the enhanced active sites in favor of N-MoS2 QDs against other samples of interest. Thereby, it is discovered that the N-doped MoS2 QD acts as an effective catalyst to notably improve the performance of the hydrogen evolution reaction (HER).

Water transmission lines have potential reserved energy, which is usually lost. Therefore, targeting this clean energy to produce electricity to power up the auxiliaries and utilities of water plants or consumers is financially and environmentally beneficial. This paper aims to investigate the feasibility of installing an inline hydropower system in an existing transmission water pipe. It analyzes the feasibility of implementing a mini-hydropower plant in the transmission line of Liwa’s reservoir in the UAE. The maximum possible power harvested is 218.175 kW at the given water flow rate and net head. The payback period and the return on investment are analyzed based on different scenarios related to capital investment, operation, maintenance cost, and plant capacity factor. It is found that the payback period ranges between one to six years, where the return on investment can be as high as 85%. Furthermore, the expected CO2 emissions saving for this project is calculated to be between 395 and 1939 tons per year.

Anticipating and relieving congestions is an ongoing challenge for transmission system operators. Distributed grid-scale battery energy storage systems enable operators to shift power flows and remedy congestion through virtual power lines and grid boosters. This paper includes battery energy storage systems in a combined preventive and curative congestion management optimization. First, it analyzes the impact of the two operational strategies in a case study of the German transmission grid. Furthermore, it outlines curative ad-hoc measures to overcome uncertainties during operational planning and real-time operation. The simulation results indicate that battery energy storage systems further increase the use of curative measures and reduce congestion management costs.

Batteries : open access battery technology & materials journal 9(1), 24 (2023). doi:10.3390/batteries9010024 special issue: "Special Issue "Redox Flow Batteries: Recent Advances and Perspectives" / Special Issue Editors: Dr. Maochun Wu, Guest Editor; Prof. Dr. Haoran Jiang, Guest Editor" Published by MDPI, Basel

The current enthusiasm for the circular economy (CE) offers a unique opportunity to advance the impact of research on sustainability transitions. Diverse interpretations of CE by scholars, however, produce partly opposing assessments of its potential benefits, which can hinder progress. Here, we synthesize policy-relevant lessons and research directions for a sustainable CE and identify three narratives-optimist, reformist, and skeptical-that underpin the ambiguity in CE assessments. Based on 54 key CE scholars' insights, we identify three research needs: the articulation and discussion of ontologically distinct CE narratives; bridging of technical, managerial, socio-economic, environmental, and political CE perspectives; and critical assessment of opportunities and limits of CE science-policy interactions. Our findings offer practical guidance for scholars to engage reflexively with the rapid expansion of CE knowledge, identify and pursue high-impact research directions, and communicate more effectively with practitioners and policymakers. Journal of Industrial Ecology, 27 (1) ISSN:1530-9290 ISSN:1088-1980

The outdoor operation of an up scaled thermally photovoltaic electrolyzer PV EC , constructed using a heat exchanger HE made of low cost materials, compared to its nonintegrated counterpart to quantify heat transfer and its effects, is studied. Thermal coupling of the PV and EC can reduce the difference between their temperatures, benefitting device performance. Such devices can produce hydrogen at rooftop installations of small to medium sized nonindustrial buildings. The devices are tested outdoors using automated real time monitoring. Under amp; 8776;880 amp; 8201;W amp; 8201;m amp; 8722;2 peak irradiance, they produced hydrogen at amp; 8776;120 and amp; 8776;110 amp; 8201;mL amp; 8201;min amp; 8722;1 rate with and without HE, respectively, corresponding to about 8.5 and 7.8 solar to hydrogen efficiencies. During about 700 amp; 8201;h of testing, the HE is beneficial at over amp; 8776;500 amp; 8201;W amp; 8201;m amp; 8722;2 due to cyclic device operation. Under lower irradiance levels, pumping previously heated electrolyte through the HE increases the PV and reduces the electrolyte temperature, reducing the device performance. The HE increases the cumulative hydrogen production amp; 8776;800 amp; 8201;L from both devices , so even relatively modest heat transfer rates can improve the PV EC operation. Improving the HE should further increase the benefits, but additional measures may be needed to maximize the hydrogen production

Refereed/Peer-reviewed In the current study, a high temperature thermal storage system with a hybrid of phase change material and graphite as the storage materials is designed and evaluated as to its applicability for use as a utility-scale Carnot battery. The design includes an externally heated liquid sodium tank, which is used as the heat transfer fluid. This is used to charge and discharge the storage system consisting of a graphite storage medium sandwiched by two phase change materials. Finally, electrical generation is by way of a supercritical carbon dioxide Brayton cycle operated at 700 °C. Detailed modelling of these designs was conducted by way of a previously validated numerical model to predict performance metrics. Using the aforementioned designs, a preliminary cost estimate was undertaken to better determine applicability. From these results, it was found that while the graphite system was the most effective at storing energy, it was also the highest cost due to the high cost of graphite. In total, 18 storage tanks containing nearly 17,400 tons of storage material were required to store the 1200 MWht required to run the sCO2 power block for 10 h. Under the study conditions, the cost of a PCM-based Carnot battery was estimated to be $476/kWhe, comparable to other storage technologies. Furthermore, it was found that if the cost of the graphite and/or steel could be reduced, the cost of the system could be reduced to $321/kWhe.