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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Europe PubMed Centra...arrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Europe PubMed Central
    Article . 1887
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Europe PubMed Centra...arrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Europe PubMed Central
      Article . 1887
      Data sources: PubMed Central
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Nobel, T. A.; Perk, K.;
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Europe PubMed Centra...arrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Europe PubMed Central
    Other literature type . 1978
    Data sources: PubMed Central
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Europe PubMed Centra...arrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
      Europe PubMed Central
      Other literature type . 1978
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Gomes, Eleni; Serzëdello, Alcides;

    A ribonuclease was partially purified from the culture medium of Aspergillus flavipes (IZ:1501), after 96 h of cultivation by chromatography on DEAE-cellulose and Sephadex G100 columns. The molecular weight of the RNase was estimated to be 40 kD by gel filtration using Sephadex G100, and the optimum pH and temperature were 4.0 and 50-55°C, respectively. Catalytic activity was inhibited by Zn+2, Fe+3, Hg+2 and Ag+ ions. The enzyme did not show an exact base specificity and produced four kinds of 3′-nucleotides from yeast RNA.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ LAReferencia - Red F...arrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ LAReferencia - Red F...arrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Domingos, Carlos Manuel Ferreira;

    Tese de mestrado integrado em Engenharia da Energia e do Ambiente, apresentada à Universidade de Lisboa, através da Faculdade de Ciências, 2014 Submitted by Cristina Manessiez (camanessiez@fc.ul.pt) on 2014-05-29T15:32:19Z No. of bitstreams: 1 ulfc106842_tm_Carlos_Domingos.pdf: 1670597 bytes, checksum: 62f841e0c14adca6f60e79681fd56717 (MD5) Made available in DSpace on 2014-05-29T15:32:26Z (GMT). No. of bitstreams: 1 ulfc106842_tm_Carlos_Domingos.pdf: 1670597 bytes, checksum: 62f841e0c14adca6f60e79681fd56717 (MD5) Previous issue date: 2014

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ LAReferencia - Red F...arrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ LAReferencia - Red F...arrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: H. Hernandez-Coronado; M. Coronado; D. Del-Castillo-Negrete;

    "The advection-diffusion equation with time dependent velocity and anisotropic time dependent diffusion tensor is examined in regard to its non-classical transport features and to the use of a non-orthogonal coordinate system. Although this equation appears in diverse physical problems, particularly in particle transport in stochastic velocity fields and in underground porous media, a detailed analysis of its solutions is lacking. In order to study the effects of the time-dependent coefficients and the anisotropic diffusion on transport, we solve analytically the equation for an initial Dirac delta pulse. We discuss the solutions to three cases: one based on power-law correlation functions where the pulse diffuses faster than the classical rate ∼ t , a second case specifically designed to display slower rate of diffusion than the classical one, and a third case to describe hydrodynamic dispersion in porous media."

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ LAReferencia - Red F...arrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ LAReferencia - Red F...arrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
  • Authors: Ebner, Florian; de Gregorio, Niko; Lato, Christiane; Ohly, Valerie; +4 Authors
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: den Otter, J.H.;

    In this thesis niobia has been shown to be an attractive support for application in Fischer-Tropsch catalysis at industrially relevant conditions without apparent deactivation up to at least 200 hours of operation. This proves that the level of potentially poisoning contaminants is sufficiently low and niobia is stable up to 260 °C and CO conversion levels higher than 80 % with concomitant high steam pressures. Niobia-supported cobalt catalysts were found to exhibit high selectivities towards liquid hydrocarbons at competitive cobalt-weight based activities. Due to the low porosity of crystalline niobia, only low cobalt loadings can be applied and consequently low catalyst-weight based activities could be obtained. However, using the reactor temperature or Pt-promotion, methods were found to compensate for the low cobalt loading and to obtain competing selectivities and catalyst-weight based activities while using a low amount of cobalt. Transition metal oxides are typical promoters added to cobalt Fischer Tropsch catalysts to enhance the selectivity towards heavy hydrocarbons. In this thesis niobia was found to be a very efficient selectivity promoter particularly at 1 bar. At 20 bar, the influence of support pore size appeared to be important. This fundamentally different role of promoters at 1 and 20 bar is very relevant to understand the necessity and role of transition metal oxide promoters in cobalt-based Fischer Tropsch catalysts but also calls for characterization methods at conditions as close as possible to industrially applied conditions, for example SSITKA at elevated pressures. Indications were found that the role of platinum in cobalt-based Fischer Tropsch synthesis was not limited to facilitation of cobalt oxide reduction but also played a role during Fischer Tropsch synthesis in PtCo/Nb2O5 catalysts. Due to the similar support nature, this observation is very relevant to Co/TiO2, a catalyst relevant for industrial Fischer Tropsch synthesis. Noble metal promoters are rarely applied in Co/TiO2 since facile and complete reduction is typical without noble metals present. Following the observations presented in this thesis, the influence of noble metal promotion on the performance of Co/TiO2 catalysts was investigated and the activity was found to be enhanced up to a factor of four upon noble metal promotion.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Utrecht University R...arrow_drop_down
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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Utrecht University R...arrow_drop_down
      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Jahrl, Ingrid; Home, Robert;

    Allotment gardens are usually managed by associations, with small allotment plots rented to individual tenant gardeners. Many garden associations have rules for organic production but the rules are neither followed nor policed. To find ways to motivate gardeners to manage their plots organically, we investigate the attitudes of Swiss gardeners towards organic gardening, and which motivations can be used to encourage and promote organic garden management. Interviews with 32 gardeners and other key informants from three Swiss target cities were analysed using content analysis. We found that organic practices are more likely when knowledge is held and that the social environment has a strong influence on behaviour, so potential exists for encouraging a culture where organic cultivation is the norm. Education strategies should therefore be developed in consultation with integration and education specialists to enhance their effectiveness by reaching their target groups in a way that encourages the cultural change.

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Organic Eprintsarrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Organic Eprints
    Conference object . 2014
    Data sources: Organic Eprints
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      Organic Eprints
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  • Authors: Streissler, Erich W. (Hrsg.); Tichy, Gunther (Hrsg.);
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Authors: Villar, J.; Kacmarek, R.M.;

    In 1994, an American-European Consensus Conference (AECC) formalized the criteria for the diagnosis of the acute respiratory distress syndrome (ARDS). Although that definition is simple to apply in the clinical setting, it has been challenged over the years in several studies since the assessment of the oxygenation defect does not require standardized ventilatory support. We were the first to propose new guidelines, based on a specific, standard method of evaluating oxygenation status, a proposal that was later advocated by others. To address the limitations of the AECC definition, a modified ARDS definition has been proposed by a task force panel of experts, referred to as the Berlin Defintion, using a terminology similar to that we previously proposed. However, that proposal has several methodological flaws. Since all ARDS patients start off with terrible oxygenation, the Berlin Definition offers no room for stratifying and identifyng true ARDS patients since there is no further re-evaluation of the hypoxemia under standard ventilator setting in a specific time period. In this Point of View, we review the history of the definition of ARDS and discussed the methodological concerns regarding adopting this new, revised ARDS definition. En 1994, una Conferencia de Consenso Americana-Europea (CCAE) formalizó los criterios para el diagnóstico del Síndrome de Distrés Respiratorio Agudo (SDRA). Aunque esa definición es sencilla de aplicar en la clínica, ha sido criticada en varios estudios ya que la medida del defecto de oxigenación no requiere de la estandarización del soporte ventilatorio. Nosotros fuimos los primeros en proponer nuevas guías basadas en un método estándar específico para evaluar el estado de la oxigenación, una propuesta que más tarde fue apoyada por otros autores. Para solucionar las limitaciones de la definición de la CCAE del SDRA, una modificación de esta definición ha sido propuesta por un panel de expertos, denominada Definición de Berlín, utilizando una terminología similar a la que nosotros habíamos propuesto previamente. Sin embargo, esta nueva propuesta tiene varios fallos metodológicos. Debido a que todos los pacientes con SDRA presentan inicialmente una oxigenación terrible, la Definición de Berlín no facilita la estratificación e identificación de verdaderos pacientes con SDRA porque no da la posibilidad de volver a evaluar el grado de hipoxemia bajo un patrón estándar de ventilación en un tiempo determinado. En este Punto de Vista revisaremos la historia de la definición del SDRA y analizaremos los problemas metodológicos relacionados con la adopción de esta nueva revisión de la definición del SDRA.

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      image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Scientific Electroni...arrow_drop_down
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  • image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ Europe PubMed Centra...arrow_drop_down
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    Europe PubMed Central
    Article . 1887
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    Authors: Nobel, T. A.; Perk, K.;
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    Other literature type . 1978
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      Other literature type . 1978
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    Authors: Gomes, Eleni; Serzëdello, Alcides;

    A ribonuclease was partially purified from the culture medium of Aspergillus flavipes (IZ:1501), after 96 h of cultivation by chromatography on DEAE-cellulose and Sephadex G100 columns. The molecular weight of the RNase was estimated to be 40 kD by gel filtration using Sephadex G100, and the optimum pH and temperature were 4.0 and 50-55°C, respectively. Catalytic activity was inhibited by Zn+2, Fe+3, Hg+2 and Ag+ ions. The enzyme did not show an exact base specificity and produced four kinds of 3′-nucleotides from yeast RNA.

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    Authors: Domingos, Carlos Manuel Ferreira;

    Tese de mestrado integrado em Engenharia da Energia e do Ambiente, apresentada à Universidade de Lisboa, através da Faculdade de Ciências, 2014 Submitted by Cristina Manessiez (camanessiez@fc.ul.pt) on 2014-05-29T15:32:19Z No. of bitstreams: 1 ulfc106842_tm_Carlos_Domingos.pdf: 1670597 bytes, checksum: 62f841e0c14adca6f60e79681fd56717 (MD5) Made available in DSpace on 2014-05-29T15:32:26Z (GMT). No. of bitstreams: 1 ulfc106842_tm_Carlos_Domingos.pdf: 1670597 bytes, checksum: 62f841e0c14adca6f60e79681fd56717 (MD5) Previous issue date: 2014

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    Authors: H. Hernandez-Coronado; M. Coronado; D. Del-Castillo-Negrete;

    "The advection-diffusion equation with time dependent velocity and anisotropic time dependent diffusion tensor is examined in regard to its non-classical transport features and to the use of a non-orthogonal coordinate system. Although this equation appears in diverse physical problems, particularly in particle transport in stochastic velocity fields and in underground porous media, a detailed analysis of its solutions is lacking. In order to study the effects of the time-dependent coefficients and the anisotropic diffusion on transport, we solve analytically the equation for an initial Dirac delta pulse. We discuss the solutions to three cases: one based on power-law correlation functions where the pulse diffuses faster than the classical rate ∼ t , a second case specifically designed to display slower rate of diffusion than the classical one, and a third case to describe hydrodynamic dispersion in porous media."

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  • Authors: Ebner, Florian; de Gregorio, Niko; Lato, Christiane; Ohly, Valerie; +4 Authors
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    Authors: den Otter, J.H.;

    In this thesis niobia has been shown to be an attractive support for application in Fischer-Tropsch catalysis at industrially relevant conditions without apparent deactivation up to at least 200 hours of operation. This proves that the level of potentially poisoning contaminants is sufficiently low and niobia is stable up to 260 °C and CO conversion levels higher than 80 % with concomitant high steam pressures. Niobia-supported cobalt catalysts were found to exhibit high selectivities towards liquid hydrocarbons at competitive cobalt-weight based activities. Due to the low porosity of crystalline niobia, only low cobalt loadings can be applied and consequently low catalyst-weight based activities could be obtained. However, using the reactor temperature or Pt-promotion, methods were found to compensate for the low cobalt loading and to obtain competing selectivities and catalyst-weight based activities while using a low amount of cobalt. Transition metal oxides are typical promoters added to cobalt Fischer Tropsch catalysts to enhance the selectivity towards heavy hydrocarbons. In this thesis niobia was found to be a very efficient selectivity promoter particularly at 1 bar. At 20 bar, the influence of support pore size appeared to be important. This fundamentally different role of promoters at 1 and 20 bar is very relevant to understand the necessity and role of transition metal oxide promoters in cobalt-based Fischer Tropsch catalysts but also calls for characterization methods at conditions as close as possible to industrially applied conditions, for example SSITKA at elevated pressures. Indications were found that the role of platinum in cobalt-based Fischer Tropsch synthesis was not limited to facilitation of cobalt oxide reduction but also played a role during Fischer Tropsch synthesis in PtCo/Nb2O5 catalysts. Due to the similar support nature, this observation is very relevant to Co/TiO2, a catalyst relevant for industrial Fischer Tropsch synthesis. Noble metal promoters are rarely applied in Co/TiO2 since facile and complete reduction is typical without noble metals present. Following the observations presented in this thesis, the influence of noble metal promotion on the performance of Co/TiO2 catalysts was investigated and the activity was found to be enhanced up to a factor of four upon noble metal promotion.

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    Authors: Jahrl, Ingrid; Home, Robert;

    Allotment gardens are usually managed by associations, with small allotment plots rented to individual tenant gardeners. Many garden associations have rules for organic production but the rules are neither followed nor policed. To find ways to motivate gardeners to manage their plots organically, we investigate the attitudes of Swiss gardeners towards organic gardening, and which motivations can be used to encourage and promote organic garden management. Interviews with 32 gardeners and other key informants from three Swiss target cities were analysed using content analysis. We found that organic practices are more likely when knowledge is held and that the social environment has a strong influence on behaviour, so potential exists for encouraging a culture where organic cultivation is the norm. Education strategies should therefore be developed in consultation with integration and education specialists to enhance their effectiveness by reaching their target groups in a way that encourages the cultural change.

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    Organic Eprints
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  • Authors: Streissler, Erich W. (Hrsg.); Tichy, Gunther (Hrsg.);
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