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  • Phase, Composition and Structure Changes of CoCrNi-Based Concentrated Alloys Resulting from High Temperature Oxidation

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    descriptionPublicationkeyboard_double_arrow_right Article 2020 Czech Republic Publisher:MDPI AG
    Authors: Monika Vilémová; Hynek Hadraba; Zdeněk Weiss; František Lukáč; +4 Authors

    doi: 10.3390/ma13102276

    pmid: 32429131

    pmc: PMC7287979

    handle: 11104/0310183

    In this work, CoCrNi, FeCoCrNi and CoCrFeMnNi concentrated alloys with a Y-Ti oxide particle dispersion were prepared by mechanical alloying and Spark Plasma Sintering. The alloy consists of an FCC Ni-based matrix with a Y-Ti oxide dispersion and additional phases of Cr23C6 and Cr2O3. The effect of Fe, Mn, and Y-Ti oxide particles on the formation of oxide scales and the composition of the adjacent CoCrNi and FeCoCrNi alloys was studied. It was found that alloys without Mn in their composition form a protective Cr2O3 scale. The Cr23C6 particles provide an alternative mechanism for balancing the chromium loss during the oxidation. Y and Ti from the oxide particles participate in the formation of the protective oxide scales. Fe promotes Y and especially Ti diffusion through the Cr2O3 scale, resulting in the formation of Ti-depleted regions in the alloy. The findings will serve for the further development of these new materials.

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    Full-Text: http://europepmc.org/articles/PMC7287979
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    License: CC BY
    Full-Text: http://www.mdpi.com/1996-1944/13/10/2276/pdf
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  • Phase, Composition and Structure Changes of CoCrNi-Based Concentrated Alloys Resulting from High Temperature Oxidation

    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
    descriptionPublicationkeyboard_double_arrow_right Article 2020 Czech Republic Publisher:MDPI AG
    Authors: Monika Vilémová; Hynek Hadraba; Zdeněk Weiss; František Lukáč; +4 Authors

    doi: 10.3390/ma13102276

    pmid: 32429131

    pmc: PMC7287979

    handle: 11104/0310183

    In this work, CoCrNi, FeCoCrNi and CoCrFeMnNi concentrated alloys with a Y-Ti oxide particle dispersion were prepared by mechanical alloying and Spark Plasma Sintering. The alloy consists of an FCC Ni-based matrix with a Y-Ti oxide dispersion and additional phases of Cr23C6 and Cr2O3. The effect of Fe, Mn, and Y-Ti oxide particles on the formation of oxide scales and the composition of the adjacent CoCrNi and FeCoCrNi alloys was studied. It was found that alloys without Mn in their composition form a protective Cr2O3 scale. The Cr23C6 particles provide an alternative mechanism for balancing the chromium loss during the oxidation. Y and Ti from the oxide particles participate in the formation of the protective oxide scales. Fe promotes Y and especially Ti diffusion through the Cr2O3 scale, resulting in the formation of Ti-depleted regions in the alloy. The findings will serve for the further development of these new materials.

    downloadFull-Text
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    Europe PubMed Central
    Article . 2020
    Full-Text: http://europepmc.org/articles/PMC7287979
    Data sources: PubMed Central
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    Materials
    Other literature type . Article . 2020 . Peer-reviewed
    License: CC BY
    Full-Text: http://www.mdpi.com/1996-1944/13/10/2276/pdf
    Data sources: Crossref; Multidisciplinary Digital Publishing Institute
    image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
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    Article . 2020
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